PHYSICAL REVIEW E 90, 062707 (2014)

ISSN: 1539-3755, SCI

Theoretical model for optical properties of porphyrin

Anh D. Phan, Do T. Nga, The-Long Phan, Le T. M. Thanh, Chu T. Anh, Sophie Bernad, and N. A. Viet

We propose a simple model to interpret the optical absorption spectra of porphyrin in different solvents. Our model successfully explains the decrease in the intensity of optical absorption at maxima of increased wavelengths. We also prove the dependence of the intensity and peak positions in the absorption spectra on the environment. The nature of the Soret band is supposed to derive from π plasmon. Our theoretical calculations are consistent with previous experimental studies.

DOI: 10.1103/PhysRevE.90.062707

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